- 14.1.1 Understand that (thermal) energy is transferred from a region of higher temperature to a region of lower temperature.
- 14.1.2 Understand that regions of equal temperature are in thermal equilibrium.
- 14.2.1 Understand that a physical property that varies with temperature may be used for the measurement of temperature and state examples of such properties, including the density of a liquid, volume of a gas at constant pressure, resistance of a metal, and e.m.f. of a thermocouple.
- Define thermal equilibrium, temperature, and thermal energy using precise scientific language.
- Explain the direction of thermal energy transfer.
- Describe how different physical properties can be used for temperature measurement.
- Discuss the concept of an empirical temperature scale.
English Term | Русский перевод | Қазақша аудармасы |
---|---|---|
Thermal Energy | Тепловая энергия | Жылу энергиясы |
Temperature | Температура | Температура |
Heat | Теплота (Тепло) | Жылу |
Thermal Equilibrium | Тепловое равновесие | Жылулық тепе-теңдік |
Transfer | Передача | Тасымалдау, беру |
Region | Область (Регион) | Аймақ |
Physical Property | Физическое свойство | Физикалық қасиет |
Thermometric Property | Термометрическое свойство | Термометрлік қасиет |
Density | Плотность | Тығыздық |
Volume | Объем | Көлем |
Pressure | Давление | Қысым |
Resistance | Сопротивление | Кедергі |
Electromotive force (e.m.f.) | Электродвижущая сила (ЭДС) | Электр қозғаушы күш (ЭҚК) |
Thermocouple | Термопара | Терможұп |
Calibration | Калибровка | Калибрлеу |
Fixed Points | Фиксированные точки (Реперные точки) | Тұрақты нүктелер (Реперлік нүктелер) |
Review the key terms using flashcards. You can find relevant sets on Quizlet or create your own:
Search for «Thermal Equilibrium & Temperature» flashcards on Quizlet
Focus on understanding the definition and application of each term.
- Thermal Energy
- The internal energy of an object due to the kinetic energy of its atoms and/or molecules. The hotter an object, the more thermal energy it has.
- Temperature
- A measure of the average kinetic energy of the particles in a substance. It indicates the
- Heat
- The transfer of thermal energy between objects due to a temperature difference. Heat always flows from a region of higher temperature to a region of lower temperature.
- Thermal Equilibrium
- A state in which there is no net flow of thermal energy between two or more objects in thermal contact. This occurs when the objects are at the same temperature.
- Thermometric Property
- A physical property of a substance that changes
- Fixed Points
- Reproducible temperatures used to calibrate a thermometer, such as the melting point of pure ice and the boiling point of pure water at standard atmospheric pressure.
1. Thermal Energy and Temperature
All matter is made up of tiny particles (atoms and molecules) that are in constant
. This motion gives them kinetic energy. Thermal energy is the total internal energy of an object associated with the kinetic energies of its constituent particles. The more the particles move or vibrate, the higher the thermal energy.Temperature is a measure of the average kinetic energy of these particles. It tells us how ‘hot’ or ‘cold’ an object is. When you touch a hot object, the fast-moving particles in the hot object transfer energy to the slower-moving particles in your hand, making your hand feel warm. Temperature is a fundamental physical quantity and is measured in Kelvin (K) in the SI system, although Celsius (°C) is also commonly used.
2. Transfer of Thermal Energy (Heat)
When two objects (or regions of the same object) at different temperatures are in thermal contact, thermal energy is
from the region of higher temperature to the region of lower temperature. This transfer of thermal energy due to a temperature difference is called heat. Heat is energy in transit; an object does not ‘contain’ heat, but it does contain thermal energy.This energy transfer will continue until both objects reach the same temperature. There are three main mechanisms for heat transfer: conduction, convection, and radiation (which will be covered in more detail in other topics).
3. Thermal Equilibrium
When objects in thermal contact no longer have a net flow of thermal energy between them, they are said to be in thermal equilibrium. This occurs when they reach the
. At thermal equilibrium, the rate of energy transfer from object A to object B is equal to the rate of energy transfer from B to A, resulting in no net change in their thermal energies.The concept of thermal equilibrium is fundamental to the Zeroth Law of Thermodynamics, which states: If two thermodynamic systems are each in thermal equilibrium with a third one, then they are in thermal equilibrium with each other. This law allows us to define and measure temperature meaningfully.
4. Measuring Temperature and Thermometric Properties
To measure temperature, we use a thermometer. A thermometer relies on a thermometric property – a physical property of a substance that changes
with temperature. For a property to be useful for thermometry, it should:- Change continuously with temperature.
- Change by a measurable amount over the desired temperature range.
- Be reproducible (i.e., the same temperature always gives the same value of the property).
- Have a unique value for each temperature.
Examples of physical properties used for temperature measurement include:
- Density of a liquid: Most liquids expand when heated (density decreases). This is the principle behind liquid-in-glass thermometers (e.g., mercury or alcohol thermometers), where the changes with temperature.
- Volume of a gas at constant pressure: According to Charles’s Law, the volume of a fixed mass of gas at constant pressure is directly proportional to its absolute temperature (V ∝ T). This is used in constant-pressure gas thermometers.
- Resistance of a metal: The electrical resistance of a metal conductor typically increases as its temperature increases. This property is used in resistance thermometers (e.g., platinum resistance thermometers). The relationship is often linear over a small range: Rθ = R0(1 + αθ), where Rθ is resistance at temperature θ, R0 is resistance at 0°C, and α is the temperature coefficient of resistance.
- Electromotive force (e.m.f.) of a thermocouple: A thermocouple consists of two different metals joined at two junctions. If the junctions are at different temperatures, a small e.m.f. (voltage) is produced, which varies with the temperature difference. This Seebeck effect is used in thermocouple thermometers, which are good for measuring a wide range of temperatures and rapidly changing temperatures.
To create a temperature scale, we need
. These are easily reproducible temperatures, such as the ice point (0°C, the temperature of pure melting ice) and the steam point (100°C, the temperature of steam from pure water boiling at standard atmospheric pressure). The Celsius scale, for example, is defined by these two points.Questions on Theory:
- Easy: What happens to thermal energy when a hot object is placed in contact with a cold object?
- Medium: Explain what is meant by ‘thermal equilibrium’ and why it is important for defining temperature.
- Medium: List three different physical properties that can be used for measuring temperature and give an example of a thermometer that uses each.
- Hard (Critical Thinking): A student suggests using the color of a heated metal bar as a thermometric property. Discuss the advantages and disadvantages of this approach for creating a precise thermometer.
Activity 1: Match the Term to its Definition
Match the terms on the left with their correct definitions on the right.
Terms: 1. Temperature 2. Thermal Equilibrium 3. Heat 4. Thermometric Property 5. Fixed Points | Definitions: A. The transfer of thermal energy due to a temperature difference. B. Reproducible temperatures used for thermometer calibration. C. A measure of the average kinetic energy of particles in a substance. D. A state of no net flow of thermal energy between objects in contact. E. A physical property that varies consistently with temperature. |
Activity 2: Fill in the Blanks
Complete the sentences below using the key terms from the lesson:
- Thermal energy always flows from a region of ______________ temperature to a region of ______________ temperature.
- When two objects are at the same temperature, they are said to be in ______________ ______________.
- The volume of a liquid, the resistance of a metal, and the e.m.f. of a thermocouple are all examples of ______________ ______________.
- A thermometer is calibrated using ______________ ______________ such as the melting point of ice.
- ______________ is a measure of the degree of hotness or coldness of an object.
This video provides a visual explanation of thermal equilibrium and temperature:
Further Viewing — Related Topics:
Example 1: Direction of Energy Transfer
A block of copper at 80°C is placed in thermal contact with a block of aluminium at 20°C in an insulated container.
(a) In which direction will thermal energy be transferred between the blocks?
(b) What condition will be met when the blocks reach thermal equilibrium?
(c) Will the final temperature be exactly 50°C? Explain your reasoning (you don’t need to calculate it).
(a) From the copper block (80°C) to the aluminium block (20°C).
(b) Both blocks will be at the same temperature. There will be no net flow of thermal energy between them.
(c) Not necessarily. It depends on the mass and specific heat capacity of each block.
(a) Direction of thermal energy transfer:
Thermal energy is always transferred from a region of higher temperature to a region of lower temperature. Since the copper block is at 80°C (higher temperature) and the aluminium block is at 20°C (lower temperature), thermal energy will be transferred from the copper block to the aluminium block.
(Textual pronunciation: Thermal energy will be transferred from the copper block to the aluminium block.)
(b) Condition for thermal equilibrium:
The blocks will reach thermal equilibrium when there is no longer any net flow of thermal energy between them. This occurs when both the copper block and the aluminium block attain the same final temperature.
(Textual pronunciation: Both blocks will attain the same final temperature.)
(c) Final temperature:
The final temperature will not necessarily be exactly 50°C (the average of the initial temperatures). The final equilibrium temperature depends on the amount of thermal energy lost by the copper block and gained by the aluminium block. This, in turn, depends on the mass (m) of each block and the specific heat capacity (c) of copper and aluminium (Q = mcΔT). If the blocks have different masses or different specific heat capacities, the temperature changes will not be symmetrical, and the final temperature will not be the simple average. For example, if the aluminium block has a much larger mass and/or specific heat capacity, it will require more energy to raise its temperature by one degree Celsius compared to the copper block, so the final temperature might be closer to 20°C than to 80°C, or vice-versa.
(Textual pronunciation: The final temperature will not necessarily be exactly fifty degrees Celsius. It depends on the mass and specific heat capacity of each block.)
Example 2: Thermometric Property — Resistance Thermometer
The resistance of a platinum wire is used as a thermometric property. At the ice point (0°C), its resistance is 10.00 Ω. At the steam point (100°C), its resistance is 13.85 Ω. Assume the resistance varies linearly with temperature between these points.
(a) Determine the temperature when the resistance of the wire is 12.50 Ω.
(b) What is the resistance of the wire at 50°C?
(a) Temperature ≈ 64.94 °C
(b) Resistance at 50°C = 11.925 Ω
Let Rθ be the resistance at temperature θ°C, R0 be the resistance at 0°C, and R100 be the resistance at 100°C.
Given: R0 = 10.00 Ω, R100 = 13.85 Ω.
Since the resistance varies linearly with temperature, we can use the formula for a straight line, or more specifically for a linear thermometric property:
θ / 100 = (Rθ — R0) / (R100 — R0)
(a) Determine the temperature when Rθ = 12.50 Ω.
Substitute the known values into the formula:
θ / 100 = (12.50 Ω — 10.00 Ω) / (13.85 Ω — 10.00 Ω)
θ / 100 = (2.50 Ω) / (3.85 Ω)
θ / 100 = 0.64935
θ = 0.64935 × 100
θ = 64.935 °C ≈ 64.94 °C (to 2 decimal places)
(Textual pronunciation: Theta divided by one hundred equals R theta minus R zero, all divided by R one hundred minus R zero. Substituting values: theta divided by one hundred equals twelve point five zero minus ten point zero zero, all divided by thirteen point eight five minus ten point zero zero. This simplifies to theta divided by one hundred equals two point five zero divided by three point eight five, which is zero point six four nine three five. So, theta equals sixty-four point nine three five degrees Celsius.)
(b) What is the resistance of the wire at θ = 50°C?
Rearrange the formula to solve for Rθ or use the same formula:
50 / 100 = (R50 — 10.00) / (13.85 — 10.00)
0.50 = (R50 — 10.00) / 3.85
Multiply by 3.85:
0.50 × 3.85 = R50 — 10.00
1.925 = R50 — 10.00
Add 10.00:
R50 = 1.925 + 10.00
R50 = 11.925 Ω
(Textual pronunciation: Fifty divided by one hundred equals R fifty minus ten point zero zero, all divided by three point eight five. So, zero point five zero equals R fifty minus ten point zero zero, divided by three point eight five. Multiplying by three point eight five gives one point nine two five equals R fifty minus ten point zero zero. Adding ten point zero zero, R fifty equals eleven point nine two five ohms.)
Explore how energy is transferred and how temperature changes using the PhET Interactive Simulation «Energy Forms and Changes».
Link to Simulation: PhET Energy Forms and Changes Simulation
Instructions:
- Open the simulation and select the «Intro» or «Systems» tab. We’ll use «Intro» for simplicity first.
- Place an iron block and a brick block on the stands.
- Check the «Energy Symbols» box to visualize thermal energy.
- You can heat or cool the blocks using the sliders underneath them. Observe the change in energy symbols (representing thermal energy) and the thermometer readings.
Tasks:
- Task 1: Heat the iron block significantly. Observe its thermometer and energy symbols. Now, place the hot iron block next to the cold brick block (or vice-versa, cool one block and heat the other, then put them in contact if the simulation allows direct contact or if you use the «Systems» tab with water between them). What happens to the energy symbols in both blocks over time? What happens to their temperatures?
- Task 2: In the «Systems» tab, place water in the beaker. Add the iron block and heat it. Observe the temperature of the water and the iron. What happens to the energy transfer when both reach the same temperature?
- Task 3: How does this simulation demonstrate the concept of thermal energy transfer and the approach to thermal equilibrium?
Work with a partner or in a small group for this activity.
Option 1: LearningApps.org Activity
Go to the following LearningApps.org activity to test your understanding of temperature and heat concepts:
Temperature and Heat — Matching Activity (Note: This is a general concepts matching game, focus on the parts relevant to today’s lesson).
Alternatively, try this one on heat transfer: Heat Transfer Methods
Discuss your answers with your partner(s) and clarify any concepts you are unsure about.
Option 2: «Explain It!» Challenge
In your group, assign one person to explain each of the following concepts to the others without looking at their notes. The listeners can ask clarifying questions.
- The difference between thermal energy and temperature.
- What it means for two objects to be in thermal equilibrium.
- How the resistance of a metal can be used as a thermometric property.
- Why fixed points are necessary for calibrating a thermometer.
Rotate roles for each concept.
Answer the following questions to test your understanding and ability to apply the concepts of thermal equilibrium and temperature. Show your working where necessary.
A student has two beakers of water. Beaker A contains 100 g of water at 20°C and Beaker B contains 200 g of water at 20°C.
(a) Compare the average kinetic energy of water molecules in Beaker A and Beaker B. Explain your answer.
(b) Compare the total thermal energy of the water in Beaker A and Beaker B. Explain your answer.
(c) If the water from both beakers is mixed in a larger insulated container, what will be the final temperature? Explain why no net thermal energy transfer occurs after mixing, assuming no heat loss to the surroundings.
Explain the principle of a thermocouple thermometer. Include in your answer:
(i) What a thermocouple is made of.
(ii) The physical phenomenon responsible for its operation (name the effect).
(iii) Two advantages of using a thermocouple for temperature measurement compared to a liquid-in-glass thermometer.
The volume of a fixed mass of gas at constant pressure is used as a thermometric property. At 0°C, the volume is 273 cm3. At 100°C, the volume is 373 cm3.
(a) On a graph of Volume (y-axis) against Temperature in °C (x-axis), sketch the expected relationship, assuming it is linear.
(b) Determine the temperature in °C when the volume of the gas is 300 cm3.
(c) What theoretical temperature does this scale predict for zero volume of the gas? What is the significance of this temperature?
Describe the key characteristics that a physical property must have to be suitable for use as a thermometric property. For one of the following properties, discuss how well it meets these characteristics: (i) the length of a metal rod, (ii) the pressure of a fixed mass of gas at constant volume.
Two objects, X and Y, are placed in thermal contact inside an insulated box. Object X has a larger mass but a smaller specific heat capacity than object Y. Initially, object X is at 10°C and object Y is at 90°C.
(a) State the direction of net thermal energy transfer.
(b) Will the final equilibrium temperature be (i) less than 50°C, (ii) equal to 50°C, or (iii) greater than 50°C? Justify your answer qualitatively without calculation, by considering the meaning of specific heat capacity and the energy changes involved.
(c) Explain what «insulated box» implies for the total thermal energy of the system (X + Y).
(Note: These questions are designed for analysis and synthesis. Focus on clear explanations and accurate calculations.)
- Save My Exams — Temperature & Thermal Equilibrium: Temperature & Thermal Equilibrium Notes
- Save My Exams — Thermometry: Thermometric Properties & Scales
- PhysicsAndMathsTutor — Thermal Physics: A-Level CIE Physics — Thermal Physics (Browse for relevant sections)
- OpenStax University Physics — Temperature and Heat: Chapter 1.1: Temperature and Thermal Equilibrium and Chapter 1.2: Thermometers and Temperature Scales
- HyperPhysics — Zeroth Law of Thermodynamics: HyperPhysics — Thermal Equilibrium and the Zeroth Law
Take a few moments to reflect on what you have learned in this lesson:
- What is the most important condition for two objects to be in thermal equilibrium?
- Can you explain, in your own words, why a physical property used for temperature measurement must change *continuously* with temperature?
- Which of the thermometric properties discussed today do you think would be most suitable for measuring very rapidly changing temperatures, and why?
- On a scale of 1 (Not at all understood) to 5 (Very well understood), how would you rate your current understanding of how thermal energy transfer leads to thermal equilibrium?
- What is one question you still have about temperature or thermometric properties, or what is one concept you would like to explore further?
I’ve included placeholders for image URLs and YouTube video URLs. You’ll need to replace `»https://youtu.be/NfEJUPnqxk0″` and similar placeholders with actual, valid URLs for the YouTube videos and images you wish to use. I’ve used some generic image URLs from `ibb.co` as examples for the solved problems, and a real PhET simulation link. The LearningApps links are also examples.
Remember to test these shortcodes within your WordPress environment to ensure they display as expected with your theme and any relevant plugins. The styling of the tooltips (`…`) is a basic suggestion; your WordPress theme or a custom CSS might offer better ways to style these.
I’ve also added some brief answers/guidance to the individual work questions within a spoiler for your reference. You might want to remove or modify this part for the student-facing version.
The YouTube video URLs I’ve put in are:
Main: `https://www.youtube.com/watch?v=g9LOhg6923g`
Related 1: `https://www.youtube.com/watch?v=x9Z2o4yYj0E`
Related 2: `https://www.youtube.com/watch?v=90Q1y3gD5Yw`
Related 3: `https://www.youtube.com/watch?v=7kyD4h90XkM`
Please replace these with your preferred videos if need